Thursday, January 21, 2021

Master Thesis in Nanotechnology with Alixlabs in Sweden on Atomic Level Fragmentation

Come and join us in Lund Sweden for an exciting Master Thesis in Atomic Level Fragmentation - the new option for extending optical lithography cheaper, greener, and faster than any advanced multi-patterning scheme!

Operating within Lind Nano Lab we guarantee a safe & flexible workplace under ISO 5 and ISO 7 Cleanroom conditions, 24/7 operation, and remote working from wherever you need to be when outside the cleanroom.

Lund Nano Lab : LINK

Thesis description and application : LINK

View across The Science City of Lund in South Sweden direction Copenhagen in Denmark across the straight of Öresend connected by the longest bridge in Europe.

Tuesday, January 19, 2021

Webinar - Enhancing Yield by Minimizing Contamination with Beneq ALD coating solutions

Yet another Webinar with Beneq, this time about ALD coating solution for your equipment.

Regsitration: LINK

Semiconductor manufacturing involves corrosive gases in multiple processes. As we transition to each new technology node, e.g. from 10nm to 7nm and to 5nm, there are even more stringent fab requirements against metal and particle contamination. This poses challenges for existing coating methods such as anodization or plasma spray, which may not provide complete protection especially on critical chamber components with complex geometry. 

This webinar is particularly helpful for process engineers, equipment engineers and others, who are responsible for contamination control and equipment yield. 

Learn more about :
  • Common issues of metal or particle contamination on critical chamber components 
  • Common coating methods against corrosion, and how they compare 
  • What properties to look for e.g. purity, uniformity, when evaluating the optimal protective coating solution 
  • Unique benefits of ALD coatings with Al2O3 and Y2O3 
  • Working with your OEM partner to design, test and implement an ALD coating solution for your equipment

Atomic Layer Deposition of 2D Metal Dichalcogenides for Electronics, Catalysis, Energy Storage, and Beyond

Here is an interesting Review from the leading ALD Laboratory at Helsinki University in Finland on 2D dichalcogenides. We are all looking forward to get to know the ALD:ed Dichalcogenides better in the future in exciting new  devices and daily life. (Thanks for sharing - Dr. King)

Atomic Layer Deposition of 2D Metal Dichalcogenides for Electronics, Catalysis, Energy Storage, and Beyond
Miika Mattinen, Markku Leskelä, Mikko Ritala
First published: 18 January 2021 in Advanced Materials Interfaces

Figure from Google cache (originally in

Abstract: 2D transition metal dichalcogenides (TMDCs) are among the most exciting materials of today. Their layered crystal structures result in unique and useful electronic, optical, catalytic, and quantum properties. To realize the technological potential of TMDCs, methods depositing uniform films of controlled thickness at low temperatures in a highly controllable, scalable, and repeatable manner are needed. Atomic layer deposition (ALD) is a chemical gas‐phase thin film deposition method capable of meeting these challenges. In this review, the applications evaluated for ALD TMDCs are systematically examined, including electronics and optoelectonics, electrocatalysis and photocatalysis, energy storage, lubrication, plasmonics, solar cells, and photonics. This review focuses on understanding the interplay between ALD precursors and deposition conditions, the resulting film characteristics such as thickness, crystallinity, and morphology, and ultimately device performance. Through rational choice of precursors and conditions, ALD is observed to exhibit potential to meet the varying requirements of widely different applications. Beyond the current state of ALD TMDCs, the future prospects, opportunities, and challenges in different applications are discussed. The authors hope that the review aids in bringing together experts in the fields of ALD, TMDCs, and various applications to eventually realize industrial applications of ALD TMDCs

Monday, January 18, 2021

RASIRC Granted Taiwan Patent for Method and Systems for Purifying Hydrogen Peroxide Solutions

Innovative new products that purify and deliver ultra-pure oxidation chemistries

SAN DIEGO, January 6, 2021 ( - RASIRC announced that the Commissioner of the Intellectual Property Office, Ministry of Economic Affairs, Republic of China has granted patent I703087 for Method and Systems for Purifying Hydrogen Peroxide Solutions. The patent is applicable to all hydrogen peroxide products including BRUTE® Peroxide and The Peroxidizer®. This invention applies the purification of the liquid source before evaporation into ultra-pure gases. Additionally, the purification improves the performance and lifetime of the patented membrane vaporizer.

“Hydrogen peroxide vapor is becoming a critical material for low-temperature processing of 3-dimensional and HAR devices as ozone and plasma methods hit their limits,” said RASIRC Chief Technology Officer Dan Alvarez. “This invention aids in our efforts to continuously improve the purity and consistency of our delivered product.”

This news comes as part of the harvest of research ideas developed over the last 15 years at RASIRC. Now moving into commercialization, this string of patents also includes our Taiwanese patent I683923, granted in April 2020, for the generation and delivery of Hydrogen Peroxide and Hydrazine gases. “These patents add to our global intellectual property footprint and are needed to support worldwide leadership in the delivery of chemistry for low-temperature oxide and nitrides,” said RASIRC Founder and CEO Jeffrey Spiegelman.

Related RASIRC Products ​

RASIRC Peroxidizer® 

The RASIRC Peroxidizer provides a safe, reliable way to deliver high-concentration hydrogen peroxide gas into ALD, annealing, dry surface preparation, and cleaning processes.

BRUTE Peroxide

Brute Peroxide is a controlled and safer chemical method to deliver high concentration hydrogen peroxide (H2O2) gas into Atomic Layer Deposition (ALD) and Etch (ALE) processes


RASIRC transforms liquids into dynamic gases that power process innovation in semiconductor and adjacent markets. By commercializing molecules for lower temperature processes, RASIRC patented technology enables the manufacture of atomic-scale oxides, nitrides, and metals. Innovative products such as Brute Peroxide, Brute Hydrazine, the Peroxidizer, and the Rainmaker Humidification Systems are being used to develop solutions for 5G, AI, IoT, and advanced automation. What makes RASIRC a unique industry leader is our technical expertise and commitment to solving complex industry challenges for our customers. Our team of industry experts has a proven track record of beating larger competitors to market by efficiently delivering state of the art technology that reduces cost, improves quality, and dramatically improves safety. With our customers at the forefront of all we do, we continue to research, develop, and design innovative products that purify and deliver ultra-pure gas from liquids for the semiconductor and related markets.

Contact RASIRC to help solve your complex problems. P: 858-259-1220, email: or visit

Tuesday, January 12, 2021

Semiconductor Materials $50B Market on a Strong Run in 2021

Semiconductor Materials $50B Market on a Strong Run in 2021Pandemic pushing people to Work From Home and School From Home

San Diego, CA, January 12, 2021: TECHCET announced that global revenues for semiconductor manufacturing and packaging materials grew approximately 4% year-over-year (YoY) in 2020 to ~US$50B, and are expected to grow ~7% in 2021 to nearly US$54B. The COVID-19 pandemic has created strong demand for both logic and memory ICs to support Work From Home (WFH) and School From Home (SFH), and such demand is expected to increase despite expanding availability of virus vaccines. Also, demand for automotive ICs has recovered and will be an important driver in 2021 growth. The compound annual growth rate (CAGR) through 2024 is forecast at 5.3% as per the latest TECHCET Critical Materials Reports (CMR) and shown in the attached figure.

Analysts' Alerts emailed to CMR purchasers help them anticipate and mitigate potential supply-chain disruptions. Excerpts have been publicly disclosed on the following critical materials (

* IPA in "CMC Considers Bio-Solvents to Reduce Fab Risks",
* HF in "Semi Wet Chemicals US$2B Market Threatened by Localization", and
* Lanthanum in "Rare Earth Elements (REE) Supply Uncertain for IC Fabs".

Picosun ALD reactors installed in Africa's first ALD-Lab at University of Johannesburg RSA

BALD Engineering has earlier reported on the first ALD-Lab in South Africa (LINK). The University of Johannesburg started a laboratory construction implementing the strategy to establish national nanotechnology in South Africa and ordering ALD Equipment from Picosun in Finland. The ALD cleanroom facility is providing an ultra-low number of particle (ISO-7) and nearly vibration- free environment for the two state-of-the-art ALD reactors (Picosun R-200 and R-200 advance), which allow the engineering squad to study numerous states and properties of various unique new nanomaterials at the atomic scale. It will be a unique building in Africa and seeks to lead the world in state-of-the-art research on nanotechnology.

According to reports (LINK) the Picosun reactors have now been delivered and installed in Johannesburg.

Rigardt Coetzee, Researcher and Coordinator at University of Johannesburg in LinkedIn: "Africa's first Atomic Layer Deposition Laboratory. The first 5nm thin film grown at atomic level. Honoured to have been the first to produce this thin film in RSA. I know these reactors will serve South Africa Well in the Industry 4.0 revolution."

Photos from the installation of the new Picosun ALD reactors in the clean rool at University of Johannesburg. Photos from LinkedIn post by Rigardt Coetzee (LINK)

Thursday, January 7, 2021

How ALD can be used to stack 2D materials on one another at a nanometer scale

TU Eindhoven latest publication to see how the toolbox of ALD can be used to stack various layered 2D materials on one another at a nanometer scale.

Surface ligand removal in atomic layer deposition of GaN using triethylgallium

Here is a paper with really impressive results on Low Temperature GaN ALD using ABC-type pulsed sequence from Henrik Pedersen group Linköping University - They insert a step between triethylgallium and ammonia to improve the deposition.

To study how to enhance the ethyl ligand removal from the surface, an additional pulse was added between the TEG and NH3/Ar plasma. This made the ALD process into an ABC-type pulsed ALD process with TEG as A-pulse, the additional gas as the B-pulse and the NH3/Ar plasma as C-pulse.

Depositions were carried out in a Picosun R-200 atomic layer deposition tool without a load lock chamber and a operating pressure of 6 hPa.

Surface ligand removal in atomic layer deposition of GaN using triethylgallium
Journal of Vacuum Science & Technology A 39, 012411 (2021);
Petro Deminskyi, Chih-Wei Hsu, Babak Bakhit, Polla Rouf, and Henrik Pedersen

Gallium nitride (GaN) is one of the most important semiconductor materials in modern electronics. While GaN films are routinely deposited by chemical vapor deposition at around 1000 °C, low-temperature routes for GaN deposition need to be better understood. Herein, we present an atomic layer deposition (ALD) process for GaN-based on triethyl gallium (TEG) and ammonia plasma and show that the process can be improved by adding a reactive pulse, a “B-pulse” between the TEG and ammonia plasma, making it an ABC-type pulsed process. We show that the material quality of the deposited GaN is not affected by the B-pulse, but that the film growth per ALD cycle increases when a B-pulse is added. We suggest that this can be explained by the removal of ethyl ligands from the surface by the B-pulse, enabling a more efficient nitridation by the ammonia plasma. We show that the B-pulsing can be used to enable GaN deposition with a thermal ammonia pulse, albeit of x-ray amorphous films.

Prof. Henrik Pedersen in the lab.

Growth per cycle (GPC) for film deposition at different temperatures (a) and with different TEG pulse time (b).

Tuesday, December 22, 2020

Nanoscale lithography of metal–organic frameworks (MOFs)

Here we have it, probably the most beautiful Journal Cover 2021 for the coming cover of the January 2021 issue of Nature Materials, by researchers from KU Leuven in Belgium, TU Munich, Vrije Universiteit Brussel, Graz University of Technology and University of Adelaide.

Nanoscale lithography of metal–organic frameworks

The low dielectric constants and high porosity of MOFs are of interest for applications in electronics and sensors, but patterning techniques for these materials are in their infancy. Here, direct X-ray and electron-beam lithography at sub-50-nm resolution are reported that leave porosity and crystallinity intact.

Tu, M., Xia, B., Kravchenko, D.E. et al. Direct X-ray and electron-beam lithography of halogenated zeolitic imidazolate frameworks. Nat. Mater. 20, 93–99 (2021).

Image: Rob Ameloot. Cover Design: Thomas Phillips.

Friday, December 18, 2020

The 200 mm Wafer Processing Equipment market is surging - who´s there fore ALD?

According to a report by Mark Lapedus (Semiconductor Engineering) there is a surge in demand for various chips is causing shortages for select 200mm foundry capacity as well as 200mm fab equipment, and it shows no signs of abating in 2021.

Foundry customers will face a shortfall of 200mm capacity at select foundries at least in the first half of 2021, and perhaps beyond. Those customers will need to plan ahead to ensure they obtain enough 200mm capacity in 2021. Otherwise they could get locked out of the market altogether, or may need to pay a premium for that capacity.

From an ALD perspective this is a very interesting market for the smaller sub Tier 1 OMEs. In this group we find interesting ALD chambers and platform moving about on the 200 mm market with limited disturbance from Applied Materials, Tokyo Electron, ASM and Lam Research. From Tier 1 the main offering is ASM A400 ALD furnaces and refurbished equipment like TEL Formulas 50 Wafer batch that was an early bird for DRAM. If you go out search the sheds around airports you should also be able to find single wafer ALD like the famous ASM Pulsar 2000, Aviza, Genus, Jusung Engineering, Genitech, Aixtron and Tegal. In summary we can find a 200 fab compatible ALD offerings from these companies and Picosun is the only company that has also made a step into 300mm (Picosun Sprinter). 

  • Arradiance : LINK 
  • Beijing NAURA Microelectronics Equipment Co.,Ltd. : LINK
  • Beneq : LINK 
  • Encapsulix  SA : LINK
  • Forge Nano (Sundew Technologies) : LINK
  • FHR Anlagenbau GmbH : LINK
  • Isac Research : LINK  
  • KE Micro : LINK
  • Korea Vacuum Tech, Ltd. (KVT) : LINK 
  • Kurt J Lesker : LINK
  • NCD : LINK
  • Oxford Instruments : LINK
  • Picosun Oy : LINK  
  • Plasma Therm : LINK
  • Sentech : LINK
  • Sundew Technologies : LINK
  • SVT Associates : LINK
  • Trion Technology : LINK
  • Veeco CNT : LINK
  • Wuxi MNT Micro and Nanotech : LINK  
  • ZLD Technology : LINK
Please get in touch for more insights to the ever evolving ALD Market!

Jonas Sundqvist, Ph.D.
Senior Technology Analyst TECHCET LLC CA (
CVD/ALD and Electronic Gases

Imec demonstrate BEOL compatible architecture that paves the way to high-density 3D-DRAM memories

LEUVEN (Belgium), 15 December 2020 — This week, at the 2020 International Electron Devices Meeting, imec, a world-leading research and innovation hub in nanoelectronics and digital technologies, presents a novel dynamic random-access memory (DRAM) cell architecture that implements two indium-gallium-zinc-oxide thin-film transistors (IGZO-TFTs) and no storage capacitor. DRAM cells in this 2T0C (2 transistor 0 capacitor) configuration show a retention time longer than 400s for different cell dimensions – significantly reducing the memory’s refresh rate and power consumption. The ability to process IGZO-TFTs in the back-end-of-line (BEOL) reduces the cell’s footprint and opens the possibility of stacking individual cells. These breakthrough results pave the way towards low-power and high-density monolithic 3D-DRAM memories.

(image: Imec)

Scaling traditional 1T1C (one transistor one capacitor) DRAM memories beyond 32Gb die density faces two major challenges. First, difficulties in Si-based array transistor scaling make it challenging to maintain the required off-current and world line resistance with decreasing cell size. Second, 3D integration and scalability – the ultimate path towards high-density DRAM – is limited by the need for a storage capacitor. Imec presents a novel DRAM architecture that responds to both challenges, thereby offering a scaling path towards low-power high-density 3D-DRAM memories.

The new architecture implements two IGZO-TFTs – which are well known for their very low off-current – and no storage capacitor. In this 2T0C configuration, the parasitic capacitance of the read transistor serves as the storage element. Resulting DRAM cells exhibit a retention time >400s thanks to an extremely low (extracted) off-current of 3x10-19A/µm. These breakthrough results were obtained for optimized scaled IGZO transistors (with 45nm gate length) processed on 300mm wafers. Optimization was directed towards suppressing the impact of oxygen and hydrogen defects on both on-current and threshold voltage – one of the main challenges for developing IGZO-TFTs.

Gouri Sankar Kar, Program Director at imec: “Besides the long retention time, IGZO-TFT-based DRAM cells present a second major advantage over current DRAM technologies. Unlike Si, IGZO-TFT transistors can be fabricated at relatively low temperatures and are thus compatible with BEOL processing. This allows us to move the periphery of the DRAM memory cell under the memory array, which significantly reduces the footprint of the memory die. In addition, the BEOL processing opens routes towards stacking individual DRAM cells, hence enabling 3D-DRAM architectures. Our breakthrough solution will help tearing down the so-called memory wall, allowing DRAM memories to continue playing a crucial role in demanding applications such as cloud computing and artificial intelligence.”

Prodrive Technologies launch Bias generator with shaped waveform for Atomic Layer Processing

Prodrive Technologies (LINK) introduces its disruptive tailored bias waveform generator to provide direct control of the sheath ion energy distribution in plasma processing. The tailored waveform output offers independent control over current and voltage and is measured in real-time. This direct control of the sheath ion energy greatly enhances the control and precision of etch and deposition processes compared to conventional RF biasing, enabling customization of ion energy distribution to allow very narrow distributions and tail elimination. This results in optimized process speed and maximum selectivity for sensitive features. It also reduces the energy consumption of the biasing, increasing the efficiency of the system with respect to conventional technologies.

Background information and the story behind the Prodrive Technology can be found here at AtomicLimits.

Nanexa AB signs USD 3 million Investment Agreement with Applied Materials to scale-up GMP production site for ALD-coated pharmaceuticals

Nanexa AB (publ) today announced that the company has entered into an investment agreement with Applied Ventures, LLC, the venture capital arm of Applied Materials, Inc., whereby Applied Ventures intends to invest up to USD 3 million in Nanexa during 2021 to support continued development and expansion. USD 1 million will be invested in January 2021 and additional investments of up to USD 2 million are planned later in 2021. The investment will be made through a directed issue to Applied Ventures of a mix of shares and share warrants decided upon by Nanexa with support of the authorization of the Annual General Meeting held on June 2, 2020 (the “Directed Issue”).

As announced today in a separate press release, Nanexa and Applied Materials have entered into a joint development agreement to validate, adapt and scale up Nanexa’s production of ALD-coated injectable drugs. Simultaneously, Nanexa has entered into an investment agreement with Applied Ventures, pursuant to which Nanexa has undertaken to, as authorized by the Annual General Meeting held on June 2, 2020, resolve to issue up to a total of 4 244 770 new shares and share warrants of series 2020/2021 in Nanexa, and Applied Ventures has undertaken to subscribe for newly issued shares and share warrants. In total, Applied Ventures has committed to invest at least USD 1 million, but the Directed Issue is intended to raise around USD 3 million before transaction costs.

“We are very pleased to welcome Applied Ventures as a new industrial investor in Nanexa. Their support is a great recognition of the PharmaShell® technology and Nanexa’s future potential,” says David Westberg, CEO of Nanexa.

The Directed Issue is divided into two tranches where the first tranche amounts to an investment of USD 1 million. The subscription price for the shares of the first tranche shall equal the volume weighted average price (“VWAP”) during the period from and including December 22, 2020 until and including January 11, 2021, less five percent. The SEK investment amount in the first tranche shall be determined by the average USD/SEK exchange rate during the same measurement period.

For the second tranche Applied Ventures has the option, but not the obligation, to exercise warrants of series 2020/2021 to subscribe for up to the number of shares equal to 4 244 770 shares less the number of shares issued in the first tranche. The warrants can be exercised during two different subscription periods; 1-15 April 2021 and 1-15 December 2021. Applied Ventures will take a decision on how many warrants to exercise in each subscription period. The subscription price in the second tranche shall equal the VWAP during the ten trading days immediately preceding the respective subscription periods, less ten percent.

The maximum potential dilution from the Directed Issue is 16.7 percent of the number of shares in Nanexa after the Directed Issue and full exercise of the issued share warrants.

“Applied Ventures is excited to invest in Nanexa and help the company scale up its unique approach of using an atomic layer deposition process on APIs to enable key benefits for the end drugs. This is a good example of how Applied’s core competency in materials engineering can be extended to new markets. It also reflects Applied Ventures’ focus on investing globally in companies across their full life-cycle and adds to our growing portfolio of investments in Europe,” said Anand Kamannavar, Global Head of Applied Ventures.

About Applied Ventures
Applied Ventures, LLC, the venture capital arm of Applied Materials, invests in innovative technology companies globally that have the potential to deliver exceptional strategic and financial returns. Its investments help develop technologies and markets that provide natural extensions to Applied Materials’ core business and stimulate the application of materials engineering for semiconductors, displays, and related products and services. Learn more at or follow @Applied_VC.

About Nanexa AB (publ) (LINK)

Nanexa AB is a nanotechnology drug delivery company focusing on the development of PharmaShell®, a new and groundbreaking drug delivery system with great potential in a number of medical indications. Within the framework of PharmaShell®, Nanexa has partnership agreements with among others, AstraZeneca.

Thursday, December 17, 2020

EU Signs €145bn Declaration to Develop Next Gen Processors and 2nm Technology

Hey listen up ALD, Santa is coming - A lot of EU funds coming in bringing Europe back in the leading edge Semiconductor game. Thank you Matthieu Weber for sharing these wonderful news in these bad times.

In a major push to give Europe pride of place in the global semiconductor design and fabrication ecosystem, 17 EU member states this week signed a joint declaration to commit to work together in developing next generation, trusted low-power embedded processors and advanced process technologies down to 2 nm. It will allocate up to €145 bn funding for this European initiative over the next 2-3 years.

Full article in EE Times Europe: LINK

While I am at it, check the planned invest for Europe in the latest Semi equipment forecast. Yes I have double checked, Europe is rolling back into the game as we speak. Following 300 mm fabs are gearing up:

  • Globalfoundries Fab1 in Dresden Germany
  • STMicro Corlles in Grenoble France
  • Infineon Dresden, Germany
  • Infineon Villach, Austria
  • Bosch Sensortech Dresden, Germany
  • Intel Leixlip,

The following results reflect market size in billions of U.S. dollars. New equipment includes wafer fab, test, and A&P. Total equipment does NOT include wafer manufacturing equipment. Totals may not add due to rounding. Source: SEMI December 2020, Equipment Market Data Subscription

Low Resistivity Titanium Nitride Thin Films ALD realized by RASIRC Brute® Hydrazine vaporization technology

TiN ALD is one of the most important ALD processes in high volume manufacturing in the semiconductor industry for more than 15 years. Most Tier 1 ALD equipment manufacturers (e.g. ASM International, Tokyo Electron , Applied Materials, Lam Research, Kokusai, Jusung Engineering, Wonik IPS, Picosun) has TiN ALD and PEALD in their process portfolio for 300 mm wafer productions targeting the Logic, 3DNAND and DRAM fab customers (e.g. Intel, Samsung, TSMC, SK Hynix, Micron, Globalfoundries, Toshiba, TI) because the metallic film has proven to be highly flexible metal film due to:

  • Relatively cheap precursor, mainly TiCl4 and TDMAT, as compared to the much more expensive precursors with lower vapor pressure for tantalum metal nitrides (PDMAT) and metals like Co (CCTBA) and Ru (RuCp´s). 
  • High vapor pressure and reactivity allowing fast conformal processing bay both CVD, pulsed CVD and ALD for TiCl4/NH3 based processes 
  • Possibility to tune low resistivity films however at relatively high temperatures (TiCl4/NH3) not allowing for BEOL thermal budget requirements (<390 °C) 
  • Excellent barrier properties hindering metal diffusion (TDMAT and TiCl4) 
  • Metal gate work function tuning by doping and partial controlled oxidation 
  • Oxygen gettering driving excess oxygen from the gate oxide channel interface into the metal gate reducing the CMOS device EOT. 
  • Mini Batch and Large Batch processing capability (e.g. TEL Indy, ASM A412, Kokusai ALDina, Picosun Sprinter)

Due to low resistivity, titanium nitride (TiN) thin films are in production as the diffusion barrier for Cu, Co and W as well as the gate metal barrier in CMOS. However, as mentioned, for high aspect ratio features, thermal ALD deposition  is needed because of high conformality. Therefore, it is very important to develop thermal ALD TiN processes further to improve the capacitor electrode, barrier and CMOS metal gate properties to perfection.

Cheng-Hsuan Kuo and co-workers at UCSanDiego in the Kummel research group, has recently concluded a study on TiN ALD utilizing the RASIRC BruteÒ Hydrazine (N2H2) vaporizer technology, which is presented this week at IEEE SISC December 16-18 (LINK).

In the work, titanium tetrachloride (TiCl4) and anhydrous hydrazine (Rasirc, Brute HydrazineÒ) were employed as the precursors with ultra-high purity nitrogen purge gas.

  • The TiN ALD chamber was connected to an in-vacuo Auger Electron Spectrometer (RBD Instruments), which was used to determine the atomic composition of ALD. (Fig. 1)
  • The sample was biased at -100V DC and Ar plasma (50W) was used to remove the surface oxides and impurities. (Fig. 2)
  • To determine resistivity, four-point probe (Ossila) measurements were performed on TiN thin films on degreased SiO2 substrates. (Fig. 3)
  • Scanning electron microscopy (SEM), ellipsometry, and X-ray reflectivity (XRR) were used to measure TiN film thicknesses. (Fig. 4)

Fig.1 Auger Electron Spectroscopy of TiN at different sputtering time.(oxygen and carbon contents are listed)

Fig. 2 Oxygen concentration and resistivity vs pulse length at 300 °C 

Fig. 3. Oxygen concentration and resistivity vs pulse length at 350 °C 

Fig.4 X-Ray Reflectivity (XRR) of the 350 oC TiN film with optimal pulse lengths 

To conclude, these experiments indicate that minimizing oxygen concentration is key in producing TiN thin films with desirable electrical properties.

The optimal resistivity of the TiN deposited at 350oC was 160 micro-ohm-cm which is the lowest reported resistivity of any TiN film deposited by thermal ALD.  As stated above the importance of 3D process capability can be met by having TiN thin films synthesized by using thermal ALD and post-plasma treatment reducing oxygen concentration and impurities potentially in very high aspect ratio structures such as contact holes, FinFET, Gate all around FETs, vias, DRAM capacitors structures as well as 3DNAND metal gates and contacts.


[1] C. H. Ahn. et al. Metals and Materials International, 7 (2001)

[2] Steven Wolf et al. Applied Surface Science 462 (2018)


This work was supported in part by the SRC



Kummel research group

EEE SISC December 16-18 (LINK).

Beneq completes new clean room facility

The new ISO 7 cleanroom will be dedicated to manufacturing ALD equipment for semiconductor and other markets with similar cleanroom requirements. The new Espoo, Finland facility includes a 350 m2 ISO 7 cleanroom and a 150 m2 ISO 5 semiconductor ALD application laboratory. 

Beneq, a supplier of atomic layer deposition (ALD) equipment for semiconductor and other industrial markets, has completed construction of a brand-new cleanroom and application laboratory at its corporate headquarters in Espoo, Finland. 

Built with the latest cleanroom design and construction technology, the new facility adds approximately 350 square meters of ISO 7 cleanroom floor space at Beneq's headquarters. It will be used for product and process development, equipment assembly, prototyping, and testing services. 

"Since the launch of the Beneq TransformTM last year we have seen great demand for our ALD equipment products from semiconductor customers,” stated Dr. Tommi Vainio, Vice President of ALD at Beneq. “Together with the semiconductor application laboratory the new cleanroom will be the engine for Beneq’s rapid growth in More-than-Moore markets, including power semiconductors, RF, image sensors, MEMS, compound semiconductors, LED & Micro-LED, OLED, and more.” 

The new cleanroom is part of Beneq’s ISO 9001 certified processes. It also houses a modern 150 square-meter semiconductor application laboratory, solely designed for developing and prototyping ALD solutions for More-than-Moore applications. Beneq has also expanded its existing cleanroom facility to ensure the highest availability and new safety features. 

The new cleanroom officially entered into production in December 2020. Prior to this facility the company had 1900 square meters of existing cleanroom capacity, which it will continue to operate for other customer markets.

Imec introduces 2D materials in the logic device scaling roadmap

[IEDM 2020 Virtual, Imec Belgium LINK] At the 2020 IEDM conference, imec proposes that 2D semiconductors like tungsten disulfide (WS2) can further extend the logic transistor scaling roadmap. The team laid the groundwork for integrating 2D semiconductors in a 300mm CMOS fab, and worked towards improved device performance. These findings are presented in four IEDM papers, one of which was selected as IEDM highlight.

More details can be found in 4 papers presented at the 2020 IEDM conference:

[1] ‘Introducing 2D-FETs in device scaling roadmap using DTCO’, Z. Ahmed et al.
[2] ‘Wafer-scale integration of double gated WS2-transistors in 300mm Si CMOS fab’, I. Asselberghs et al.
[3] ‘Dual gate synthetic WS2 MOSFETs with 120µS/µm Gm 2.7µF/cm2 capacitance and ambipolar channel’, D. Lin et al.
[4] ‘Sources of variability in scaled MoS2 FETs’, Q. Smets et al. (IEDM highlight paper)

TEM image of a 2D device fabricated with 300mm processes. (Source: Imec)

Friday, December 11, 2020

KLA Introduces Two New Systems that Take On Semiconductor Manufacturing's Toughest Problems

MILPITAS, Calif., Dec. 10, 2020 /PRNewswire/ -- Today KLA Corporation (NASDAQ: KLAC) announced two new products: the PWG5™ wafer geometry system and the Surfscan® SP7XP wafer defect inspection system. The new systems are designed to address exceedingly difficult issues in the manufacture of leading-edge memory and logic integrated circuits.

KLA’s new PWG5™ patterned wafer geometry metrology system and Surfscan® SP7XP unpatterned wafer defect inspection system support development and production of advanced logic, DRAM and 3D NAND devices.

Stacked ever higher, like molecular skyscrapers, the most capable flash memory is built in an architecture called 3D NAND. Today's 96-layer top-of-the line memory chips, already on the market in the most advanced mobile devices, will soon be superseded by 3D NAND structures with 128 or more layers in the ongoing quest for increased space-efficiency and cost-effectiveness. To manufacture these complex structures requires depositing hundreds of thin films of multiple materials, and then creating memory cells by etching and filling holes several microns deep and one-hundredth of a micron across. As these film stacks grow higher, they induce stress on the wafer, ultimately distorting the surface planarity of the wafer. These warped wafers impact the uniformity of downstream processes and patterning integrity, ultimately affecting final device performance and yield. The PWG5 metrology system can measure minute distortions of wafer geometry with unprecedented resolution to identify and correct patterned wafer distortion at the source. Moreover, these critical wafer geometry measurements can now be accomplished for large warp ranges at inline speeds.

"The complex multilayer construction of 3D NAND has moved wafer geometry measurements to the forefront," said Jijen Vazhaeparambil, general manager of the Surfscan and ADE division at KLA. "Our new patterned wafer geometry system, the PWG5, has the sensitivity to measure any deviations from planarity on the front side and back side of the wafer simultaneously. Its first-of-a-kind inline speed and exceptional resolution support not only 3D NAND, but also advanced DRAM and logic applications. Coupled with KLA's 5D Analyzer® data analytics system, the PWG5 helps our customers drive decisions, such as wafer re-work, process tool re-calibration, or alerting the lithography system so that best possible patterning corrections can be applied. The PWG5 system plays a critical role in process control, helping grow advanced memory and logic yield, performance and fab profitability."

On the leading-edge logic side of the semiconductor industry, high volume manufacturing of 5nm node devices is rising while the 3nm node is under development.* EUV lithography has become nearly universal for the most critical layers within these nodes, and device manufacturing is further complicated by novel geometries like finFET or gate all around (GAA) transistor architectures. Patterning such small, complex features in a repeatable way, billions of times across a wafer, requires exquisite defectivity control, including use of unpatterned wafer inspectors for careful qualification of starting substrates and materials, and frequent monitoring of processes and tools. The new Surfscan SP7XP unpatterned wafer defect inspection system features advancements to sensitivity and throughput, and introduces machine learning-based defect classification that together enable capture and identification of an even wider range of defect types on an even wider range of blanket films and substrate types than the benchmark Surfscan SP7.

Vazhaeparambil added, "The Surfscan design team focused not only on technical advances to support sensitivity and defect classification, but also on improving the cost of ownership." As a result, the Surfscan SP7XP represents a single-tool solution for unpatterned wafer inspection applications from R&D to high volume manufacturing of leading-edge design node substrates and devices. It is in use at silicon wafer manufacturers, semiconductor equipment manufacturers developing defect-free processes, and semiconductor fabs for ensuring incoming wafer, process and tool quality.

To maintain their high performance and productivity, Surfscan SP7XP and PWG5 systems are backed by KLA's global comprehensive service network. For more information about the technology advances that enable the PWG5 and Surfscan SP7XP systems' new capabilities, and to read about applications of the systems beyond those described here, visit the KLA Advance newsroom.

*The node nomenclature used by the semiconductor industry correlates to the smallest dimension of the transistor. For comparison 3nm is about half the diameter of the DNA double-helix.

Surfscan and 5D Analyzer are registered trademarks of KLA Corporation.

Thursday, December 10, 2020

ALD Webinar - The Ultimate Anti-Corrosion Coating Solution presented by Beneq

Join this webinar featuring ALD (atomic layer deposition) pioneer Beneq to learn about the unique benefits of ALD for critical chamber components with complex geometry, and how the technology offers the ultimate anti-corrosion coating solution for semiconductor equipment parts.

Wednesday, January 27, 2021, 9:00 AM – 10:00 AM CET

If you can't attend the live session, register for access to a recording for later viewing.

Semiconductor manufacturing involves corrosive gases in multiple processes. As we transition to each new technology node, e.g. from 10nm to 7nm and to 5nm, there are even more stringent fab requirements against metal and particle contamination. This poses challenges for existing coating methods such as anodization or plasma spray, which may not provide complete protection especially on critical chamber components with complex geometry. 

Topics to be discussed:
  • Common issues of metal or particle contamination for critical chamber components
  • Common coating methods to protect against corrosion, and how they compare
  • What properties to look for – e.g. high purity and uniformity – when evaluating the optimal protective coating solution
  • Unique benefits of ALD coatings with Al2O3 and Y2O3
  • How to work with your OEM partner to design, test and implement an ALD coating solution for your equipment

Agenda and Speaker Information

Sponsored by

[PALD] SUMMIT Video Library is now available on demand - Enjoy!

The 2nd [PALD] Summit by Forge Nano is now happening. This is following the first very successful event earlier in 200 and Forge Nano is planning yet a 3rd event i summer 2021. More information will come in the near future.

Anyhow, the [PALD] SUMMIT Video Library is now available on demand - Enjoy!

------ [PALD] SUMMIT on Demand LINK ------

Presentation by BALD Engineering during the first [PALD] Summit

Horizontal high temperature rotating graphite drum furnace for ALD and LPCVD on particles and powders BALD Engineering AB: Jonas Sundqvist

Wednesday, December 9, 2020

MSS Corp Low temp ALD the solution for analyzing extreme ultraviolet photoresist

MSS launches new materials analysis items: "ALD sample preparation" for 5nm ~ 2nm EUV PR & Low-k materials

MSS launches new materials analysis items: "ALD sample preparation" for 5nm ~ 2nm EUV photoresist & Low-k materials process structure and composition analysis! All the loyal customers can still keep ALD sample preparation technical services with the same the price. On the other hand, the customers will be applicable to the quotation of new analysis service items.

[MSS Corp article] Atomic layer deposition (ALD) has attracted considerable attention in integrated circuit (IC) equipment industry in recent years. This is largely due to its superior properties, excellent coating conformity, and controllable coating thickness in single atomic layer, especially when compare to other coating systems.

Today, ALD has turned into a core technology in IC fabrication processes and its significance has become even more pronounced as a result of its advanced fabrication processes, including such modern solutions as 3D FinFET or even future gate-all-around (GAA), along with all other variants where precisely well-controlled coating thickness and thin film conformity in sub-nanometer level are in high demanded.

Apart from the above applications in IC fabrication, ALD can also be used for material analysis. A good example in this regard would be the transmission electron microscope (TEM), where by ALD is used to prepare a protection layer on top of areas of interest (AOI) before TEM lamella preparation. Here, it is well known that TEM lamellas are mainly prepared by focused ion beam (FIB). In order to protect AOI from ion bombardment during FIB milling, an external protection layer on top of AOI is indispensable. The material within this protection layer is generally carbon-based glues or metals, and the layer thickness varies from tens of nanometers up to about 500 nm. This protection layer can be coated on surface of AOIs by spin coaters or deposition systems in a vacuum chamber.

Now, depending on coating mechanisms, sample temperature and ion bombardment effects are two main factors that should be considered in order to prevent structures of AOI being altered or damaged during coating processes. For older technology nodes (bigger than 28 nm node), such coating can be easily achieved with wider preparation windows. This is because both the material and structure of AOI are relatively robust and stable. Generally speaking, coating with normal preparation conditions leads to no obvious structural changes or damages of the AOI when observing TEM results.

In terms of advanced technology nodes (below 16 nm node), continuous shrinkage of critical dimension (CD) along with the fact that many new materials are now involved in the fabrication processes are important factors to consider. For instance, extreme ultraviolet (EUV) photoresist (PR) has become one of the most crucial materials used in fabrication processes of 7 nm (and below) node FinFET and future GAA. However, it has been widely reported that EUV PR is extraordinarily fragile and highly sensitive to temperature and ion (both polarities). Damaged or deformed AOIs are expected to be found by traditional coating for older technology nodes, and pristine structures no longer exist for further analysis.

Coating conformity can also be problematic for structures with smaller CDs, such as vias or trenches, when using traditional methods. Extrinsic pinholes or bubbles are expected to be formed before vias or trenches being fully filled with the coating material. These unwanted artifacts could lead to possible difficulties in terms of preventing curtain effect during FIB milling and afterwards when it comes to TEM data interpretation.

To solve all of the above listed challenges, MSS proposes an innovative approach – utilizing a low-temperature vacuum ALD approach to prepare the protection layer on surface of AOIs. Because of its growth mechanism, ALD has an excellent coating conformity, so it is perfectly fitted for coating materials into vias, trenches, or other structures with smaller CDs.

When it comes to preventing damages from FIB milling and following TEM observation (high-energy electron damages), a thicker protection layer is preferred – at least 50 nm in thickness. This is because the thick protection layer is like a powerful armor and has a strong resistance to FIB milling and high-energy electron bombardment. Depending on surface properties of AOIs and analytic purposes, different protection materials can be prepared. Most importantly, despite varieties of protection materials, the sample temperature must always be kept at a low temperature throughout preparation – only a bit higher than room temperature, but certainly well below the one utilized in traditional coating systems. It is crucial, especially for EUV PR because all these steps have to ensure EUV PR stays intact throughout the whole analysis flow and precise results can be delivered.

Figure 1. a-d TEM images of PR structures. Two different types of PR structures were utilized a, b and c, d. The protection layers in a and c were prepared by the traditional coating and those in b and d were prepared by MSS ALD coating. In a and c, obviously, the PR structures were damaged or altered by comparing with those in b and c, see the areas marked by green arrows.

Figures 1a and 1c exhibit TEM images taken from two different PR samples. Their protection layers were all prepared by the traditional coating method. Poor coating conformity can be observed, especially in Fig. 1c. For comparison, an MSS low-temperature vacuum ALD has been utilized on another two samples with the same structures and materials as Figs. 1a and 1c. The TEM images are shown in Figs. 1b and 1d, respectively. From these TEM images, it is easy to see the PR structures prepared by the traditional coating have been damaged or modified, especially the areas marked by green arrows, with certain degree by comparing with the ones prepared by MSS ALD.

The question here now becomes how best to prove the low-temperature vacuum ALD coating has no effects on modifying PR structures as shown in Figs.1 a and 1c. To answer this question, we utilized one of our niche analyses, non-coating high-resolution SEM, to observe the pristine sample before ALD coating and the result is shown in Fig. 2a. The same sample was then coated with MSS ALD followed by FIB milling and TEM observation, and the result is shown in Fig. 2b. The fact that the PR structure shown in Fig. 2a is consistent with the one shown in Fig. 2b observed by TEM strongly suggests the PR structure does not need to be altered or damaged with our ALD preparation.