CHESTNUT HILL, MA (February 25, 2015) - To power a car so it can
travel hundreds of miles at a time, lithium-ion batteries of the future
are going to have to hold more energy without growing too big in size.
That's one of the dilemmas confronting efforts to power cars through
re-chargeable battery technologies. In order to hold enough energy to
enable a car trip of 300-500 miles before re-charging, current
lithium-ion batteries become too big or too expensive.
Chemists from Boston College and UMass Amherst applied two nano-scale
coatings to a unique form of carbon, known as 3DOm. The resulting boost
in 3DOm's stability produced performance gains that could lead to the
material's use in lithium-air batteries. (Image : Boston College)
In the search for the "post-lithium-ion" battery, Associate
Professor of Chemistry Dunwei Wang has been developing materials that
might one day enable the manufacture of new batteries capable of meeting
power demands within the size and cost constraints of car makers and
other industries.
In a recent report published in the German journal Angewandt Chemie (Abstract below),
Wang and a colleague from the University of Massachusetts Amherst
unveiled a new method of stabilizing carbon - a central structural
component of any battery - that could pave the way to new performance
standards in the hunt for a lithium-ion components.
Central to the search for improved performance is the ability to
shed weight and costly chemical components. Researchers pursuing a
"lithium-air" battery have focused on a chemical reaction of lithium
and oxygen, which can be pulled from the air. But the materials used to
generate this reaction have shown poor life cycles, lasting through just
a few charges.
Boston College chemist Dunwei Wang
The culprit, said Wang, is the instability of carbon, an essential
structural support to a battery's electrode, a conductor where charges
collect and dispense.
"Carbon is used in every battery because it has that combination of
low cost, light weight and conductivity," said Wang. "You can't just
scrap it."
So Wang and UMass Assistant Professor of Chemical Engineering Wei
Fan set to work improving the performance capabilities of a newly
engineered form of carbon fabricated by Fan. It's called
three-dimensionally ordered mesoporous (3DOm) carbon and scientists
value it for its highly ordered structure.
Employing a technique called atomic layer deposition (ALD), the
researchers grew a thin coating of iron oxide on the carbon, a step that
enhanced the reactivity between lithium and oxygen and improved
performance on the charge cycle. Next, they used ALD to apply a coating
of palladium nanoparticles, which effectively reduced carbon's
deteriorative reaction with oxygen and improved the discharge cycle.
Their initial tests on the material showed marked improvement in performance. "We demonstrated that a particular form of carbon can be used to
support a new type of chemistry that allows for energy storage with the
promise of five to 10 times more energy density than state-of-the-art
lithium-ion batteries we see today," said Wang. "We see this as
significantly improving the cyclability of the battery, which is a key
issue."
Wang said the findings show 3DOm carbon can meet new performance standards when it is stabilized.
"The key innovation we make here is that 3DOm carbon is stable - we
have stabilized something that was not previously stable," said Wang.
Three Dimensionally Ordered Mesoporous Carbon as a Stable, High-Performance Li–O2 Battery Cathode
Jin Xie, Xiahui Yao, Qingmei Cheng, Ian P. Madden, Paul Dornath, Chun-Chih Chang, Prof. Dr. Wei Fan, Prof. Dr. Dunwei Wang
Article first published online: 10 FEB 2015
DOI: 10.1002/ange.201410786
Enabled by the reversible conversion between Li2O2 and O2, Li–O2 batteries promise theoretical gravimetric capacities significantly greater than Li-ion batteries. The poor cycling performance, however, has greatly hindered the development of this technology. At the heart of the problem is the reactivity exhibited by the carbon cathode support under cell operation conditions. One strategy is to conceal the carbon surface from reactive intermediates. Herein, we show that long cyclability can be achieved on three dimensionally ordered mesoporous (3DOm) carbon by growing a thin layer of FeOx using atomic layer deposition (ALD). 3DOm carbon distinguishes itself from other carbon materials with well-defined pore structures, providing a unique material to gain insight into processes key to the operations of Li–O2 batteries. When decorated with Pd nanoparticle catalysts, the new cathode exhibits a capacity greater than 6000 mAh gcarbon−1 and cyclability of more than 68 cycles.
Three Dimensionally Ordered Mesoporous Carbon as a Stable, High-Performance Li–O2 Battery Cathode
Jin Xie, Xiahui Yao, Qingmei Cheng, Ian P. Madden, Paul Dornath, Chun-Chih Chang, Prof. Dr. Wei Fan, Prof. Dr. Dunwei Wang
Article first published online: 10 FEB 2015
DOI: 10.1002/ange.201410786
Enabled by the reversible conversion between Li2O2 and O2, Li–O2 batteries promise theoretical gravimetric capacities significantly greater than Li-ion batteries. The poor cycling performance, however, has greatly hindered the development of this technology. At the heart of the problem is the reactivity exhibited by the carbon cathode support under cell operation conditions. One strategy is to conceal the carbon surface from reactive intermediates. Herein, we show that long cyclability can be achieved on three dimensionally ordered mesoporous (3DOm) carbon by growing a thin layer of FeOx using atomic layer deposition (ALD). 3DOm carbon distinguishes itself from other carbon materials with well-defined pore structures, providing a unique material to gain insight into processes key to the operations of Li–O2 batteries. When decorated with Pd nanoparticle catalysts, the new cathode exhibits a capacity greater than 6000 mAh gcarbon−1 and cyclability of more than 68 cycles.