Showing posts with label ALD - Atomic Layer Deposition. Show all posts
Showing posts with label ALD - Atomic Layer Deposition. Show all posts

Saturday, April 12, 2025

Neumonda and Ferroelectric Memory Company Collaborate in the Commercialization of Non-Volatile DRAM

Neumonda and Ferroelectric Memory (FMC) are working together to design, provide test solutions, and market FMC’s nonvolatile DRAM+. This collaboration aims nothing less than to bring semiconductor DRAM memory design and manufacturing back to Germany.


Marco Mezger, COO of Neumonda, Thomas Rueckes, CEO of FMC, and Peter Poechmueller, CEO of Neumonda (from left to right), celebrate the collaboration of the two German memory powerhouses


Two German memory innovators join forces to bring semiconductor memory back to Germany

Bad Homburg / Dresden, April 3, 2024 – Neumonda and Ferroelectric Memory (FMC) are working together in the design, provision of test solutions, and marketing of FMC’s nonvolatile DRAM+. This collaboration aims nothing less than to bring semiconductor DRAM memory design and manufacturing back to Germany.

FMC commercializes a disruptive technology that combines non-volatile properties of ferroelectric hafnium oxide (HfO2) with RAM to create a non-volatile DRAM memory for AI, medical, industrial, automotive, and consumer applications. As part of the agreement, Neumonda which holds several patents in the design and testing of DRAM memory, will support FMC with memory consulting services and with its Rhinoe, Octopus, and Raptor test platforms for FMC’s nonvolatile DRAM+ products.

“FMC was founded to exploit the disruptive invention of the ferroelectric effect of HfO2 for semiconductor memories. Applied to a DRAM, it turns the DRAM capacitor into a low power, nonvolatile storage device while maintaining the high DRAM performance to produce a disruptive nonvolatile DRAM memory ideal for AI compute,” explained Thomas Rueckes, CEO of FMC. “Since our technology is unique in the market, cost-effective testing of our memory products is of great importance for our product offerings. With Neumonda and its radically new approach to testing, we have found a partner that can help us speed up the development of our products. We also are excited to work with Neumonda as we share the common vision to bring Memory back to Europe”

Neumonda combines unmatched expertise in memory and, with its Neumonda Technology division, revolutionizes memory testing. Its testers are lightweight, low-cost, and energy-efficient and enable Neumonda to conduct manufacturer-independent tests at a level and detail that has not been possible before—all this at a fraction of the costs of traditional testers.

“As our test platforms are maturing, FMC’s products are an ideal test ground to prove the capabilities of our Rhinoe, Octopus, and Raptor testers, as well as the high-quality yield they enable,” explained Peter Poechmueller, CEO of Neumonda. “One of my personal goals behind founding Neumonda was to bring semiconductor memory back to Europe. With this collaboration, we take a big step closer to establishing a new German memory manufacturer.

About FMC

FMC was founded in 2016 as a spin-off from NaMLab GmbH, a TU Dresden company, to commercialize ferroelectric hafnium oxide technology originally invented by Qimonda, the former German DRAM manufacturer. FMC is a full stack fabless semiconductor company with operations in Dresden (Germany), Milan (Italy) and North America. FMC product offerings include high density, low power, nonvolatile DRAM and Cache chiplets for disruptive performance and power efficiency improvements in edge and cloud AI systems. Since its foundation, FMC has been working closely with Saxonian, Federal German and European funding providers and is very thankful for this continuous support. For more information visit: www.ferrolectric-memory.com

About Neumonda

NEUMONDA combines extensive memory experience with the “DNA” of former memory manufacturer Qimonda, with the aim to offer the most extensive portfolio of specialized memory solutions and competence in the market. It governs MEMPHIS Electronic, a distributor of memory ICs and modules of different suppliers; Intelligent Memory, the manufacturer of DRAM and NAND-based memory solutions; and NEUMONDA Technology which designs and holds IP for application test systems for memory applications. Combining these different areas of expertise, NEUMONDA is able to offer unique global memory competency that can help companies in any industry to meet their current and future memory requirements. www.neumonda.com

Monday, March 17, 2025

3rd and Last Call for Papers, and List of Speakers / Symposium on ALD & ALE Applications #21, at 248th ECS Fall Meeting / Oct. 12-16, 2025 in Chicago, USA

This fall, the 248th ECS Meeting will be held on Oct. 12-16, 2025 in Chicago (IL, USA), and is expected to gather some 3,000 participants and 40 exhibitors from both academia and industry.

The conference has a strong focus on emerging technology and applications in both solid-state science & technology and electrochemistry.



The organizers of symposium G01 on “Atomic Layer Deposition & Etching Applications, 21” encourage you to submit your abstract(s) on topics, comprising but not limited to: 

1. Semiconductor CMOS applications: development and integration of ALD high-k oxides and metal electrodes with conventional and high-mobility channel materials; 
2. Volatile and non-volatile memory applications: extendibility, Flash, MIM, MIS, RF capacitors, etc.; 3. Interconnects and contacts: integration of ALD films with Cu and low-k materials; 
4. Fundamentals of ALD processing: reaction mechanisms, in-situ measurement, modeling, theory; 
5. New precursors, delivery systems & sustainability issues; 
6. Optical, photonic and quantum applications; applications aiming at Machine Learning, Artificial Intelligence 
7. Coating of nanoporous materials by ALD; 
8. Molecular Layer Deposition (MLD) and hybrid ALD/MLD; 
9. ALD for energy conversion applications such as fuel cells, photovoltaics, etc.; 
10. ALD for energy storage applications; 
11. Productivity enhancement, scale-up and commercialization of ALD equipment and processes for rigid and flexible substrates, including roll-to-roll and spatial processing; 
12. Area-selective ALD; 
13. Atomic Layer Etching (‘reverse ALD’) and related topics aiming at self-limited etching, such as atomic layer cleaning, etc. 

FYI: Last year at the PRiME 2024 Meeting in Honolulu, our symposium G01 on ALD & ALE Applications 20 attracted some 80 participants, attending a full 3-days schedule with 50 presentations (42 oral, of which 16 invited, plus 8 poster presentations). We expect to be at least as successful this Fall in Chicago. 

Abstract submission 
Meeting abstracts should be submitted not later than the deadline of March 28, 2025 via the ECS website: Submission Instructions

Submission Instructions Invited speakers A list of invited speakers follows below: 



Visa and travel For extensive information, see last year’s version: VISA AND TRAVEL INFORMATION

In addition, ECS’ Francesca Di Palo (francesca.dipalo@electrochem.orgcan provide you with an official participation letter issued by the Electrochemical Society. For (limited) general travel grant questions, please contact travelgrant@electrochem.org

As in the past years, we expect also our symposium to be able provide some partial travel allowance to selected speakers. We are looking forward to meeting you all at our symposium G01 on ALD & ALE Applications 21, in Chicago | Oct. 12-16, 2025!

Sunday, March 16, 2025

Bridging the Lab-to-Fab Gap: Overcoming ALD Scaling Challenges with Chipmetrics, Finland

Scaling Atomic Layer Deposition (ALD) from laboratory research to high-volume semiconductor manufacturing presents numerous challenges, particularly as the industry moves towards more complex 3D structures like 3D NAND, Through-Silicon Vias (TSVs), and nanosheet transistors. One major hurdle is the disparity between lab-scale process development and industrial fabrication, where variations in chamber design and wafer size can lead to unexpected process deviations. Additionally, throughput and cost considerations play a critical role, as slow deposition rates can hinder industrial adoption due to high operating expenses. Defect control is another key concern, as even minuscule particle contamination can significantly impact yield, yet many research facilities lack the advanced defect detection capabilities necessary for high-volume manufacturing. Furthermore, test structure availability is a limiting factor, with sub-100 nm, high-aspect-ratio structures often restricted to leading semiconductor manufacturers, creating barriers for process validation and qualification.


Chipmetrics' PillarHall® metrology chips offer an innovative solution to these challenges by providing dedicated test structures with aspect ratios up to 10,000:1, allowing for rapid and cost-effective ALD validation without the need for complex cross-sectional analysis. These metrology chips facilitate the development of high-aspect-ratio thin film depositions by enabling researchers and manufacturers to evaluate process performance in a scalable manner, ensuring compatibility with industrial requirements. Beyond technical validation, the ability to conduct precise, non-destructive measurements enhances efficiency and reduces development costs, accelerating the transition from lab to fab. As semiconductor manufacturing continues to evolve, tools like PillarHall play a crucial role in streamlining the process transfer while maintaining the precision and reliability demanded by the industry.


PillarHall LHAR4 Test Chip in animated presentation. How to use the PillarHall chip in characterizing 3D thin film process conformality. Lateral High Aspect Ratio, Ultra High Aspect Ratio, Thin Film, Conformal, Deposition, Atomic Layer Processing, Atomic Layer Deposition, Chemical Vapor Deposition, ALD, CVD, HAR, 3D, metrology, Atomic Layer Etching, ALE


In this insightful presentation given by the inventor of PillarHall test chips, Professor Riikka Puurunen from the School of Chemical Engineering, Department of Chemical and Metallurgical Engineering at Aalto University, talks about "Recent Progress in Analysis of the Conformality of Film by Atomic Layer Deposition.

Source:

Challenges of Transferring Deposition Processes to Industry Partners in the Semiconductor Industry - Chipmetrics

ALD FOR INDUSTRY 2025: Advancing Atomic Layer Deposition from Science to Industrial Applications in Dresden

The 8th International Conference "ALD for Industry" took place in Dresden from March 11 to 12, 2025, bringing together experts to discuss advancements in Atomic Layer Deposition (ALD) technology. In addition to the previously mentioned presentations, the conference featured several notable talks:

Prof. Fred Roozeboom

AlixLabs and Aether Semiconductor

Silicon Austria Labs

ASM International

The handshake

Prof. Riikka Puurunen


"Fundamentals of Atomic Layer Deposition: A Tutorial" by Prof. Riikka Puurunen

Prof. Riikka Puurunen from Aalto University, Finland, delivered a comprehensive tutorial on the fundamentals of ALD. She covered the history of ALD, its underlying surface chemistry, typical reaction mechanisms, and growth modes. Prof. Puurunen also discussed the role of diffusion in 3D structures and provided insights into surface reaction kinetics.


In her tutorial titled "Fundamentals of Atomic Layer Deposition," Prof. Riikka Puurunen of Aalto University provided a comprehensive overview of ALD, a nanotechnology technique for precise surface modifications and thin coatings. She traced ALD's dual origins: Atomic Layer Epitaxy (ALE) developed by Tuomo Suntola in 1974, and Molecular Layering (ML) introduced by Valentin Aleskovskii and Stanislav Koltsov in the 1960s. The tutorial delved into the core principles of ALD, emphasizing its reliance on repeated, self-terminating reactions between gaseous reactants and surfaces. Prof. Puurunen categorized typical reaction mechanisms, discussed factors influencing saturation and growth modes, and highlighted "growth per cycle" (GPC) as a fundamental characteristic of ALD processes. She also explored the role of diffusion in complex 3D structures, noting how diffusion-limited growth can provide insights into surface reaction kinetics. The presentation available at Fundamentals of ALD: tutorial, at ALD for Industry, Dresden, by Puurunen 2025-03-11 | PPT

"Spatial ALD of IrO₂ and Pt Films for Green H₂ Production by PEM Electrolysis" by Dr. Paul Poodt

Dr. Paul Poodt, Chief Technology Officer at SparkNano, presented on the application of spatial ALD in fabricating iridium dioxide (IrO₂) and platinum (Pt) films. These materials are crucial for enhancing the efficiency of proton exchange membrane (PEM) electrolyzers used in green hydrogen production. Dr. Poodt highlighted how spatial ALD enables precise control over film thickness and composition, leading to improved performance and durability of electrolyzer components.


SparkNano’s CTO, Paul Poodt, presented on Spatial ALD of IrO₂ and Pt Films for Green H₂ Production by PEM Electrolysis on March 12 at 10:20 AM during the Emerging Applications session. Attendees had the opportunity to connect with him to discuss SparkNano’s spatial ALD technology.

"Advancements in ALD for Next-Generation Semiconductor Devices" by Dr. Christoph Hossbach

Dr. Christoph Hossbach from Applied Materials / Picosun Europe discussed recent progress in applying ALD techniques to next-generation semiconductor devices. His presentation covered the integration of ALD processes in manufacturing advanced transistors and memory devices, emphasizing the role of ALD in achieving atomic-scale precision and conformality required for modern microelectronics. 


"ALD Applications in Quantum Technology" by Dr. Martin Knaut

Dr. Martin Knaut of TU Dresden explored the utilization of ALD in developing components for quantum technologies. He highlighted how ALD's ability to deposit uniform and defect-free thin films is essential for fabricating qubits and other quantum devices, potentially leading to more stable and scalable quantum computing systems. 

"Emerging Applications of ALD in the Medical Field" by Dr. Mira Baraket

Dr. Mira Baraket from Atlant 3D presented on the potential of ALD in medical applications, including the development of biocompatible coatings for implants and drug delivery systems. She discussed how ALD can enhance the performance and safety of medical devices by providing precise control over surface properties.


Sources:

ALD for Industry 2025 – EFDS

Friday, February 7, 2025

JSR Expands Global Semiconductor Material Capabilities with New Photoresist Facilities, Advanced MOR Variants, and Strategic Acquisition of CVD/ALD Precursor Firm

JSR Corporation is expanding its global development and production of advanced photoresists by establishing a new R&D center in Japan and constructing a semiconductor photoresist plant in Korea. Since acquiring Inpria Corporation in 2021, JSR has been commercializing Metal Oxide Resist (MOR) for EUV lithography. The new R&D center in Japan’s Kanto region will enhance collaboration with global customers and partners, while the Korean plant, expected to begin operations in 2026, will handle the final production process for MOR to support local adoption. JSR aims to drive innovation in photoresists and help customers establish commercial production processes worldwide.

JSR's MOR, developed through its 2021 acquisition of Inpria Corporation, is a next-generation photoresist designed for EUV lithography. MOR is based on metal oxide nanoparticles, offering superior etch resistance and improved pattern resolution compared to traditional chemically amplified resists (CARs). This allows for finer feature definition and reduced line-edge roughness, critical for advanced semiconductor manufacturing below 10 nm. JSR has been scaling MOR for commercial adoption, with major semiconductor manufacturers evaluating its use in high-volume production. The company is expanding its R&D and manufacturing capacity, including a new R&D center in Japan and a production facility in Korea, to support global adoption of MOR.



JSR have investigated different flavors of MOR for EUV lithography, primarily focusing on variations in metal cores and process optimizations. Initially, zirconium (Zr) and hafnium (Hf) based MORs were explored, but their relatively low EUV absorption led researchers to investigate alternative metal cores such as titanium (Ti), zinc (Zn), indium (In), and tin (Sn). These new metal cores exhibited improved lithographic performance, achieving higher EUV absorption, smaller particle size, and better scum reduction. Additionally, process optimizations such as using higher dissolution rate photoacid generators (PAGs), new organic solvent developers, and lower soft bake temperatures were tested to improve scum removal and resolution. The new metal core variants demonstrated resolutions down to 13 nm with reduced defects, suggesting their potential for advanced semiconductor manufacturing.

In August 2024, JSR Corporation completed the acquisition of Yamanaka Hutech Corporation (YHC), a Kyoto-based manufacturer specializing in high-purity chemicals for semiconductor manufacturing. This strategic move allows JSR to expand its product portfolio to include Chemical Vapor Deposition (CVD) and Atomic Layer Deposition (ALD) precursors, which are essential for forming advanced and complex semiconductor device structures. YHC, established in 1960, has over 60 years of experience in advanced molecular design, synthesis technology, and quality control systems, supplying high-quality CVD/ALD precursors to leading-edge semiconductor device manufacturers. The acquisition aligns with JSR's strategy to strengthen its position as a global supplier of semiconductor materials, enhancing its capabilities in both miniaturization and device structure innovation.

Sources:

JSR Expands Global Development and Production Functions for Leading-Edge Photoresists | 2024 | News | JSR Corporation

tec125-4.pdf

High-Precision ALD and Etching Techniques Enable Sub-1nm EOT in Monolayer MoS₂ Transistors

Researchers from Stanford University and Yonsei University have investigated the role of silicon seed layers in enabling high-quality atomic layer deposition (ALD) of HfO₂ on monolayer MoS₂, achieving sub-nanometer equivalent oxide thickness (EOT) and precise threshold voltage control.

Researchers developed a method to achieve sub-1 nm equivalent oxide thickness (EOT) in monolayer MoS2 transistors using atomic layer deposition (ALD) of HfO2 with a silicon seed layer, enabling improved threshold voltage control and low hysteresis. They investigated six seed layer candidates (Si, Ge, Hf, La, Gd, Al2O3) and found that only Si and Ge preserved the integrity of MoS2. The Si seed provided the best interface, allowing for the fabrication of normally-off transistors with a well-behaved threshold voltage. The resulting devices demonstrated a low EOT of approximately 0.9 nm, minimal leakage current (<0.6 μA/cm²), and a subthreshold swing of ~80 mV/dec at room temperature. This method offers a simple and accessible approach to depositing high-quality top-gate dielectrics in common nanofabrication facilities.


The manufacturing process of monolayer MoS2 transistors in the study involves several key steps, including atomic layer deposition (ALD) and etching processes:

  1. MoS2 Growth and Device Preparation: Monolayer MoS2 is synthesized using chemical vapor deposition (CVD) at 750°C on a SiO2 (90 nm) / p++ Si substrate. Alignment markers are deposited, and large contact pads (SiO2/Ti/Pd) are patterned and lifted off.

  2. Channel Patterning and Etching: The transistor channels are defined via electron-beam lithography and etched using xenon difluoride (XeF2) chemistry. Gold source and drain contacts are then deposited using electron-beam evaporation.

  3. Seed Layer Deposition: For the top-gate structure, ultrathin Si and Ge seed layers (~1 nm) are deposited using e-beam evaporation under high vacuum (~10⁻⁷ Torr). These seed layers are exposed to air before undergoing characterization via Raman and XPS measurements.

  4. Atomic Layer Deposition (ALD) of HfO₂: The Si or Ge-seeded samples are placed in the ALD chamber at 200°C for 30 minutes before initiating the deposition process. HfO₂ is grown using tetrakis(dimethylamido)hafnium (TDMAH) and H₂O as precursors at 200°C. The ultrathin Si seed oxidizes into SiOx, forming a high-quality interface for dielectric growth.

  5. Top-Gate Metallization and Etching: The Pd top gate is patterned and deposited using e-beam evaporation. To expose the contact pads for probing, the top-gate oxide is selectively removed using inductively coupled plasma (ICP) etching with CF₄.

  6. Annealing: The top-gated devices undergo vacuum annealing at 150°C, while back-gated devices without top gates are annealed at 250°C for two hours to remove moisture and stabilize electrical characteristics.

This process enables the formation of high-quality MoS₂ transistors with sub-1 nm equivalent oxide thickness (EOT), low leakage, and precise threshold voltage control.



Sources:

Sub-Nanometer Equivalent Oxide Thickness and Threshold Voltage Control Enabled by Silicon Seed Layer on Monolayer MoS2 Transistors | Nano Letters

nl4c01775_si_001.pdf

Wednesday, February 5, 2025

TU Eindhoven and LONGi Advance ALD ZnO Passivating Contacts, Achieving 24.3 Percent Efficiency in Silicon Solar Cells

Atomic layer deposition of ZnO for contact passivation in silicon solar cells has emerged as a promising alternative to TOPCon technology, with the recent breakthrough of zinc oxide passivating contacts achieving 24.3 percent efficiency in a LONGi solar cell. This development builds on research led by Bart Macco’s group at Eindhoven University of Technology, which pioneered the concept of ZnO passivating contacts. The breakthrough was further demonstrated by LONGi, which successfully integrated the technology into high-efficiency solar cells.


Key advancements include the use of an interfacial SiO2 layer for passivation, Al2O3 capping to retain hydrogen during annealing, and selective Al2O3 removal to enable electrical contact while preserving passivation. The integration of a low-work-function LiF layer has improved contact resistivity, reducing the need for heavy silicon doping.

ALD ZnO offers lower-temperature processing, thinner layers around five nanometers, and elimination of toxic dopants compared to doped poly-Si in TOPCon. With potential advantages in scalability, industrial feasibility, and initial efficiency gains, ZOPCon could surpass TOPCon, though further research is needed to enable bifacial designs, optimize lateral conductivity, and enhance stability for large-scale production.


Sources

Passivating Contacts for Silicon Solar Cells: A Zinc Oxide Breakthrough? – Atomic Limits

Tuesday, February 4, 2025

Jusung Engineering Records Strong Financial Performance and Expands ALD Equipment Shipments in 2024

Jusung Engineering Ltd. (KOSDAQ:036930) maintains a strong financial position with a net cash balance of ₩187.2 billion, as its cash reserves of ₩232.2 billion significantly exceed its ₩45.0 billion in debt. Despite total liabilities exceeding cash and receivables by ₩109.4 billion, the company's market capitalization of ₩1.37 trillion suggests that these obligations do not pose a substantial risk. Jusung Engineering's EBIT grew by an impressive 211% over the past year, further strengthening its ability to manage debt. Additionally, with free cash flow amounting to 80% of EBIT over the last three years, the company demonstrates solid cash flow management, reducing concerns over its debt burden. Given these factors, Jusung Engineering appears financially stable, with strong earnings and liquidity to support future growth.


Jusung Engineering shipped atomic layer deposition equipment for DTC silicon capacitor production on the 17th of last month.

In May 2024, Jusung Engineering unveiled plans to restructure its business by spinning off its semiconductor, solar, and display divisions into separate entities. The strategic move aimed to enhance operational efficiency and create greater shareholder value. However, by October 2024, the company decided to cancel the spin-off due to opposition from shareholders. The total stock purchase price for the stocks exercised in opposition exceeded KRW 50 billion, leading to the decision to maintain the company's current structure.

Beyond its financial success, Jusung Engineering made notable advancements in its technology offerings. In November 2024, the company shipped Atomic Layer Deposition (ALD) equipment for the production of Deep Trench Capacitor (DTC) Silicon Capacitors to Elspeth. 

Jusung Engineering's strong financial results, strategic decisions, and technological advancements reinforce its position as a key player in the global semiconductor industry. 

References:
https://www.mk.co.kr/en/business/11231493
https://www.businesskorea.co.kr/news/articleView.html?idxno=216376
https://www.marketscreener.com/quote/stock/JUSUNG-ENGINEERING-CO-LTD-6494704/news/JUSUNG-ENGINEERING-Co-Ltd-cancelled-the-Spin-Off-of-Semiconductor-equipment-research-and-developme-48189649/
https://www.mk.co.kr/en/business/11164246

Friday, January 31, 2025

Forge Nano Expands ALD Capabilities with New TEPHRA™ Cluster Tool and State-of-the-Art Cleanroom

Forge Nano has significantly expanded its semiconductor atomic layer deposition (ALD) capabilities with the completion of a new 2,000 sq ft cleanroom dedicated to manufacturing its TEPHRA™ ALD cluster tools. This expansion comes in response to increased demand for high-throughput ALD solutions in the 200mm wafer market, particularly for advanced packaging, power semiconductor, and microelectromechanical system (MEMS) applications. The new facility, featuring Class 10 (ISO 4) cleanroom space and a dedicated metrology lab, will enable Forge Nano to accelerate production, conduct customer demonstrations, and validate ALD process integration for commercial-scale adoption.



The TEPHRA™ cluster tool is designed to deliver ultrathin, uniform coatings with 10x the throughput of traditional ALD systems, supporting applications such as conformal metal barrier seed layers for through-silicon and through-glass vias (TSVs and TGVs). With customer tool deliveries expected in early 2025, Forge Nano is inviting industry partners to on-site demonstrations showcasing TEPHRA’s capabilities. This expansion reinforces Forge Nano’s position as a key enabler of next-generation semiconductor manufacturing, offering efficient and scalable ALD solutions for the growing demand in advanced node technologies.

Sources:

Thursday, January 30, 2025

Lam Research’s Dry Resist: A Breakthrough in EUV Lithography for Next-Generation Logic and Memory Manufacturing

Lam Research’s dry resist technology represents a major shift in EUV lithography and semiconductor patterning, addressing critical challenges such as stochastic defectivity, resolution limitations, and cost-efficiency. With recent qualifications for advanced DRAM and 2nm logic manufacturing, along with a growing ecosystem for high-volume production, dry resist is positioned to disrupt traditional chemically amplified resists (CARs) and enable future High-NA EUV adoption.

One of the most significant recent developments is Lam’s qualification of dry resist for 28nm pitch BEOL logic at 2nm and below in collaboration with imec. This qualification confirms that dry resist can eliminate multi-patterning steps, reducing complexity and improving EUV throughput. The process is designed to work with both low-NA and high-NA EUV scanners, ensuring its relevance for sub-2nm logic scaling. This represents a key milestone in extending direct EUV printing to future logic nodes, an approach that could significantly lower lithography costs while improving pattern fidelity.


In addition, a leading DRAM manufacturer has selected Lam’s Aether dry resist technology as its production tool of record for advanced DRAM nodes. This decision highlights dry resist’s low-defect, high-fidelity patterning capabilities, which are essential for scaling memory architectures. The technology enables lower exposure doses while reducing stochastic defects, which are a major concern in EUV-based DRAM production. Given that Samsung, SK Hynix, and Micron are all increasing their reliance on EUV for next-generation DRAM, Lam’s dry resist is well-positioned for widespread adoption in the memory sector.


To ensure a stable supply chain for dry resist materials, Lam Research has partnered with Entegris and Gelest, a Mitsubishi Chemical Group company. This collaboration ensures reliable dual-source precursor production, providing chipmakers with long-term process stability. The partnership also focuses on the development of next-generation high-NA EUV precursors, further strengthening dry resist’s role in future sub-2nm manufacturing.


SEM images of 28 nm pitch line/space patterns imaged with 0.33NA EUV in dry resist from Entegris precursor.

A critical enabler of dry resist technology is its atomic layer deposition (ALD) process, which replaces traditional spin-coating used in CARs. ALD-based vapor-phase deposition offers higher uniformity, eliminating polymer chain variations found in conventional resists. It also allows precise thickness control, which is essential for optimizing EUV photon absorption and etch selectivity. Unlike CARs, which rely on a complex mixture of polymers, dry resist materials are based on single-component metal-organic precursors such as organo-tin oxides. These materials provide higher EUV photon absorption, improving sensitivity and pattern resolution.

Another key advantage of dry resist is its anisotropic dry development process, which replaces wet solvent-based development. Traditional CAR-based EUV resists require organic solvents or aqueous bases, leading to stochastic defects, material loss, and waste. Dry resist, by contrast, is developed entirely in the gas phase, selectively removing unexposed regions and forming a negative-tone image. This eliminates line collapse and delamination issues, improving yield stability. Additionally, the elimination of wet chemistries significantly reduces chemical waste, making dry resist a more sustainable solution with five to ten times lower material consumption compared to traditional resists.

Lam’s dry resist technology is poised to disrupt traditional CAR-based EUV lithography, particularly as the industry moves toward High-NA EUV adoption. By reducing multi-patterning dependency, the technology enhances cost-effective EUV scaling, making it an attractive solution for both logic and memory manufacturers. This positions Lam as a key leader in next-generation EUV resist solutions, challenging conventional resist suppliers like JSR, TOK, and Inpria.

From a sustainability perspective, dry resist significantly lowers EUV exposure dose requirements, leading to higher scanner throughput and lower energy consumption. Its reduced defectivity translates to higher yield per wafer, further enhancing cost-efficiency. The collaboration with Entegris and Gelest ensures supply-chain stability, making dry resist a viable and scalable technology for sub-2nm nodes.

The patent US20220020584A1 mentions several Lam Research tools that play a role in the dry resist deposition, patterning, and development process for EUV lithography. The Altus system is referenced for deposition, likely for metal or dielectric films in the dry resist stack, while the Striker plasma-enhanced atomic layer deposition (PEALD) system may be used for precise resist or underlayer deposition. The Versys platform, known for plasma processing, is relevant to the dry development process, and the Syndion system, typically used for deep silicon etching, may have applications in pattern transfer. Additionally, the Reliant tool is designed for volume manufacturing, possibly adapted for integrating dry resist technology, and the Kiyo plasma etch system is likely involved in etching after the dry resist development stage. These tools collectively enable Lam’s dry resist process to achieve improved resolution, defect reduction, and cost efficiency in advanced EUV lithography.

The patent US20220020584A1, filed by Lam Research Corporation, describes an innovative dry development process for EUV photoresists, which eliminates the need for traditional wet chemical development methods. The patent details a dry resist system deposited via vapor-phase precursors, forming a highly uniform, single-component material that enhances EUV photon absorption and sensitivity. The dry development process selectively removes unexposed resist regions using plasma-based or plasma-free chemical methods, significantly reducing line collapse and defectivity while improving resolution at sub-2nm nodes. By integrating dry resist deposition, EUV exposure, and dry development into a single cluster tool, the patented technology enables scalable, high-volume EUV manufacturing with lower chemical consumption and improved process sustainability, positioning it as a key enabler for High-NA EUV lithography.

Lam Research’s dry resist technology represents a significant development in EUV lithography by addressing key challenges in stochastic defectivity, process cost, and sustainability. Its qualification for 2nm logic and advanced DRAM manufacturing confirms its readiness for high-volume production. By utilizing ALD for precise resist deposition and securing a stable precursor supply through partnerships with Entegris and Gelest, Lam has established a strong foundation for scaling the technology. 

Sources:

Lam Research Press Release on DRAM Adoption (Jan 2025): Lam Research
imec Qualification of Dry Resist for 2nm Logic (Jan 2025): imec
Entegris and Gelest Collaboration Announcement (July 2022): Entegris
Overview of Dry Resist ALD and Precursor Chemistry: SemiAnalysis
ASML High-NA EUV Roadmap and Implications for Dry Resist: ASML
Lam Reserach patent application US20220020584A1: US20220020584A1.pdf


Friday, January 17, 2025

3D Vertical Ferroelectric Capacitors for Memory Scaling

3D vertical ferroelectric capacitors are revolutionizing memory technology, offering higher density and performance by leveraging vertical structures to overcome planar scaling limits. Using aluminum-doped hafnium oxide (Al:HfO₂), these capacitors achieve stable remnant charge, low voltage operation, and enhanced scalability, addressing advanced applications in AI and edge computing. Recent innovations, such as the TiN/Al:HfO₂/TiN configuration introduced by Dongguk University, South Korea, demonstrate improvements in endurance and integration. This progress builds on foundational work by Qimonda and Fraunhofer IPMS-CNT in Dresden Germany, including Tim Böscke's pioneering discovery of ferroelectricity in hafnium oxide and Johannes Müller's ALD advancements using ALD process developments FHR and ASM tools. These developments cement Al:HfO₂ as a DRAM and CMOS-compatible solution for next-generation non-volatile memory technologies.

3D vertical ferroelectric capacitors are transforming memory technology by providing higher density and performance in compact designs. Leveraging a vertical structure, they overcome planar scaling limits by using the third dimension to maximize storage capacity. Incorporating ferroelectric materials like aluminum-doped hafnium oxide (Al:HfO₂) enables these capacitors to achieve spontaneous polarization and stable remnant charge even at reduced dimensions. With features like low voltage, high-speed operation, and improved retention and endurance, they address critical challenges in advanced memory while remaining compatible with CMOS processes, facilitating their integration into existing manufacturing technologies. This innovation is key to meeting the demands of data-intensive applications such as AI and edge computing.

A recent study, 3D Vertical Ferroelectric Capacitors with Excellent Scalability (by Eunjin Lim et al Dongguk University, South Korea)), introduces a 3D vertical ferroelectric capacitor with a TiN/Al:HfO₂/TiN configuration. It employs a unique architecture with multiple small holes sharing a common pillar electrode, enhancing ferroelectric properties and scalability. Analyses using advanced microscopy confirm its structural integrity, while the device demonstrates high endurance, minimal variability, and excellent retention. This architecture also supports integration into one-transistor n-capacitor ferroelectric memory with vertical transistors.

Importantly, Earlier work by Fraunhofer IPMS-CNT, including the 2012 study Incipient Ferroelectricity in Al-Doped HfO₂ Thin Films, first demonstrated ferroelectric properties in HfO₂ thin films doped with aluminum. This research identified an antiferroelectric-to-ferroelectric phase transition, influenced by Al concentration and annealing conditions, and attributed ferroelectricity to a non-centrosymmetric orthorhombic phase (Pbc2₁). This foundational work highlighted the potential of Al:HfO₂ for applications in memory and sensing technologies.


The later paper High Endurance Strategies for Hafnium Oxide-Based Ferroelectric Field Effect Transistors further emphasized Al:HfO₂’s scalability and compatibility with CMOS technology. It explored strategies to improve endurance and reduce interfacial stress, including modifying interfacial materials and exploring MFS structures. These strategies balance performance, reliability, and scalability, supporting the broader adoption of ferroelectric memory.


In Johannes Müller's PhD thesis (2014, Fraunhofer IPMS-CNT), the Atomic Layer Deposition (ALD) processes for hafnium oxide (HfO₂) and aluminum-doped hafnium oxide (Al:HfO₂) utilized advanced deposition equipment to achieve precise doping and phase control. The processes were performed using a 300 mm FHR ALD 300 and an ASM PULSAR 3000®, both of which are designed for high-uniformity deposition on large substrates, such as 300 mm wafers. These tools facilitated the use of tetrakis(ethylmethylamino)hafnium (TEMAHf) and trimethylaluminum (TMA) as precursors for hafnium and aluminum, respectively, along with oxidants like water or ozone. By tailoring precursor ratios, deposition temperatures, and annealing conditions, the processes ensured the stabilization of the orthorhombic Pbc2₁ phase, critical for the ferroelectric properties of Al:HfO₂ films. These advancements highlight the scalability and compatibility of ALD-fabricated Al:HfO₂ films with CMOS technology.


Semiconductor Cleanroom Tools: Introducing ASM Eagle XP4 for ALD | Fraunhofer IPMS


Historic picture of the FHR ALD 300 mm tool, at the previous location of Fraunhofer IPMS-CNT. The FHR cluster was co-developed by Qimonda and Fraunhofer CNT and teh original discovery of ferroelectric hafnium oxide was by Qimonda and a PhD Student from TU Dresden, Tim Böscke. His groundbreaking work, published in 2011, demonstrated the ferroelectric properties of silicon-doped hafnium oxide (Si:HfO₂), marking a major milestone in the development of CMOS-compatible ferroelectric materials. This discovery laid the foundation for integrating ferroelectric properties into hafnium oxide-based systems, revolutionizing non-volatile memory technologies

The patent US 2009/0057737 A1, authored by Tim Böscke et al., describes a method for fabricating integrated circuits with a dielectric layer that exhibits enhanced properties, such as high dielectric constants and ferroelectricity. The process involves forming a preliminary dielectric layer, such as hafnium oxide or doped hafnium oxide (e.g., aluminum- or silicon-doped), using techniques like Atomic Layer Deposition (ALD). The dielectric layer is initially amorphous and undergoes a phase transition to a crystalline state upon heating above its crystallization temperature. The method includes precise doping of the dielectric layer to stabilize desirable phases, such as orthorhombic or tetragonal, which are essential for achieving ferroelectricity. A covering layer, often a conductive electrode material, is deposited before annealing to assist in crystallization and enhance material properties. The innovations outlined aim to improve memory applications, such as capacitors and transistors, by offering higher storage densities, lower leakage currents, and compatibility with advanced CMOS processes. This patent is foundational in the development of ferroelectric hafnium oxide-based technologies.

Sources:

Friday, January 10, 2025

Game-Changing ALD Breakthrough: KJLC Achieves First Scandium Nitride PEALD Process

Revolutionizing Atomic Layer Deposition: Kurt J. Lesker Company's Groundbreaking ALD Publication
January 08, 2025 | By KJLC Innovate 

In the ever-evolving world of semiconductor technology, innovation is the key to staying ahead. At Kurt J. Lesker Company, we are proud to announce a groundbreaking achievement that promises to revolutionize the field of Atomic Layer Deposition (ALD). Our latest publication, featuring the patented Precursor Focusing Technique (PFT) and Ultra-High Purity (UHP) process capability, marks a significant milestone in our commitment to advancing next-generation applications.


The First of Its Kind: Scandium Nitride by PEALD

For the first time, scandium nitride (ScN) has been successfully deposited using plasma-enhanced atomic layer deposition (PEALD) on silicon, sapphire, and magnesium oxide substrates under UHP conditions. This innovative process utilizes a new scandium precursor, bis(ethylcyclopentadienyl)scandium-chloride [ClSc(EtCp)2], combined with N2-H2 plasma species, allowing for the deposition of high-quality ScN films at relatively low temperatures (200−300°C).


Why This Publication is a Game-Changer

The significance of this publication lies in its potential to transform various advanced electronic applications. The ScN films produced by this process exhibit high crystalline quality and excellent electrical properties, with high mobility and low resistivity. These characteristics make them suitable for a wide range of applications, including thermoelectric devices and as an interlayer for epitaxial gallium nitride (GaN) growth.

Moreover, the ability to conformally coat high aspect ratio (HAR) structures is particularly valuable for applications in 3D embedded memory and piezoelectric microelectromechanical systems (piezoMEMS). Traditional sputtering techniques are not suitable for these applications involving complex 3D architectures, making this new ALD process a significant advancement.


The Commercial Relevance of ScN

Scandium nitride is commercially relevant primarily because it forms a solid solution with aluminum nitride (AlN), resulting in aluminum scandium nitride (Al1-xScxN), which enables ferroelectric switching. Al1-xScxN thin films are traditionally deposited via reactive magnetron sputtering, which yields highly c-axis oriented columnar grains. However, sputtering is not suitable for coating high-aspect ratio (HAR), vertically layered structures such as those desired for use in 3D embedded memory.

Recently, there have been several reports of piezoelectric AlN grown by atomic layer deposition (ALD) techniques that have shown promising crystalline quality and properties. However, there are no reports of ALD Al1-xScxN, principally because there are no reported ALD processes for ScN. This publication addresses this gap, providing a new method for depositing high-quality ScN films.
Looking Ahead

As KJLC continues to push the boundaries of ALD technology, we are excited about the possibilities our new research and development opens up. From thermoelectrics to applications involving high-aspect ratio (HAR) architectures such as 3D embedded memory and piezoMEMS technology, the high crystalline and electrical quality demonstrated here for ScN by PEALD techniques is just the beginning.

Sources:








Wednesday, January 8, 2025

ALD for Industry | International Conference & Exhibition - March 11 - 12, 2025 | Dresden, Germany

ALD for Industry | International Conference & ExhibitionMarch 11 - 12, 2025 | Dresden, Germany
+++ Poster Submission, Early Bird Registration & Exhibition Booking +++
Deadline: January 31, 2025

Atomic Layer Deposition is an important technology for surface modification and structuring. Again we will discuss recent developents and applications of the technology in March in Dresden. Already 26 speakers confirmed their contributions. Check the first anounnced talks and use the earyl bird registration until January 31, 2025.



Also Poster Submissions and booking of exhibition places is possible until January 31, 2025. Present your services and products to the ALD Community and become visible to interested people.

More information you can find the the ALD Website: https://lnkd.in/eKt86GV7


Program Preview

We are pleased to announce first speakers of the upcoming event. A complete porgram will be published in January 2025Fundamentals of atomic layer deposition: a tutorial| Riikka Puurunen, Aalto University, Sweden

  • Industrial batch ALD for optical applications | Shuo Li, Afly Solution Oy, Finland
  • Direct Processing by µDALP™. Precision Coatings for Next Gen Devices | Maksym Plakhotnyuk, ATLANT 3D, Denmark
  • Nanoscale solid-state lithium-ion electrolytes enabled by atomic layer deposition | Messaoud Bedjaoui, CEA Leti, France
  • Fabrication of Surface Relief Gratings using ALD-based Technologies to Overcome the Challenges of Reactive Ion Etching of TiO2 | Mathias Franz, Fraunhofer ENAS, Germany
  • Monitoring and optimisation of ALD processes with Remote Plasma Optical Emission Spectroscopy | Erik Cox, Gencoa Ltd, UK
  • Optimizing Plasma-Assisted Atomic Layer Deposition using Impedans RFEAs | Angus McCarter, Impedans Ltd., UK
  • Improving atomic layer deposition process of silicon oxide (SiO2) and aluminum oxide (Al2O3) | Long Lei, Fraunhofer IMPS, Germany
  • Introducing a Surface Acoustic Wave-Based Miniaturized Aerosol Source for Controlled Liquid Precursor Delivery in ALD Processes | Mehrzad Roudini, Leibniz IFW, Germany
  • Challenges and Solutions in ALD of Thermal Budget Sensitive Ferroelectric Materials | Bart Vermeulen, Ferroelectric Memory Co GmbH, Germany
  • ALD for Nanoparticles: From Fundamentals to Industrial Applications | Rong Chen, University of Science and Technology HUST, China
  • Recent developments and emerging applications in atmospheric-pressure ALD on high-porosity membranes | Fred Roozeboom, University of Twente, Netherlands
  • Past, present and future of ALD from an industrial perspective | Jan Willem Maes, ASM, Belgium
  • Advanced in-situ QCM process monitoring | Martin Knaut, ALS Metrology UG, Germany
  • Cryogenic Atomic Layer Etching (Cryo-ALE) of low-k dielectrics like SiO2, and GaN etching. | Rémi Dussart, Université d´Orleans, France
  • ALD for Memory Applications: a matter of details | Laura Nyns, IMEC, Belgium
  • Spatial ALD of IrO2 and Pt films for green H2 production by PEM electrolysis | Paul Poodt, SparkNano B. V., The Netherlands
  • APECS Pilot Line – Advanced Packaging and Heterogeneous Integration for Electronic Components and Systems | Wenke Weinreich, Fraunhofer IPMS, Germany
Program Committee
  • Sean Barry, Carleton University, Canada
  • Gloria Gottardi, Fondazione Bruno Kessler, Italy
  • Christoph Hossbach, Applied Materials / Picosun Europe, Germany
  • Martin Knaut, TU Dresden, Germany
  • Laura Nyns, IMEC, Belgium
  • Fred Roozeboom, University Twente, Netherlands
  • Jonas Sundqvist, Alixlabs, Sweden
POSTER Exhibition

The Poster Submission is open until January 31, 2025. Please send us an Abstract for your Poster Application. PO001 | Deposition of High Quality Aluminium Fluoride Layers through Optimization of a PEALD Process using Al(CH3)3 and SF6 | Fabian Steger, RhySearch, Buchs, Austria PO002 | Evaluating the Enhanced Fire Resistance of Polyamide Fabric through Dual-Layer Treatment with ALD-ZnO and DOPO-Based Silane | Sebastian Lehmann, Leibniz IFW, Germany

Surface Passivation: A Cornerstone for Advancing Semiconductor Technologies

Modern semiconductor devices like transistors, solar cells, microLEDs, and thin-film transistors all rely heavily on effective surface passivation to enhance performance. As devices continue to evolve toward 3D architectures and smaller form factors, managing surface defects becomes critical to maintaining efficiency. Surface passivation, achieved through thin films deposited by atomic layer deposition (ALD) or similar techniques, minimizes charge carrier recombination at surface sites, thereby boosting the overall performance of semiconductor devices. The latest review paper by Bart Macco, published in the Journal of Vacuum Science and Technology A, provides a comprehensive analysis of surface passivation techniques across silicon, germanium, and III–V materials. The study highlights the importance of atomic-scale processing methods, such as ALD and atomic layer etching (ALE), in meeting the demands of advanced semiconductor architectures. It also explores the emerging trends in high-volume manufacturing of ALD Al₂O₃ layers, novel passivation stacks tailored for different semiconductor materials, and the growing role of in-situ cleaning processes. This review underscores how advancements in passivation methods are shaping next-generation semiconductor devices, addressing both performance and reliability challenges. For more details, the paper is open access and licensed under Creative Commons Attribution and you can also check out the recent post in AtomicLimiuts.com (links below).




Sources: 
Macco, B., et al. "Surface passivation approaches for silicon, germanium, and III–V semiconductors." Journal of Vacuum Science and Technology A.: Surface passivation approaches for silicon, germanium, and III–V semiconductors | Journal of Vacuum Science & Technology A | AIP Publishing

Saturday, January 4, 2025

2025 Book - Emerging Atomic Layer Deposition for Hydrogen Energy

The book "Emerging Atomic Layer Deposition for Hydrogen Energy" highlights several key applications where Atomic Layer Deposition (ALD) will play a transformative role in advancing hydrogen energy systems. In hydrogen production, ALD is utilized to improve water-splitting catalysts, including both electrochemical and photoelectrochemical (PEC) methods. By coating electrodes with thin, uniform layers, ALD enhances the efficiency and stability of the catalytic process. ALD is also applied to photoelectrodes in solar-driven water splitting to improve light absorption, charge separation, and durability. Additionally, ALD is used to modify proton exchange membranes (PEMs), enhancing their chemical stability and proton conductivity in fuel cells and electrolyzers.



In hydrogen storage, ALD plays a significant role by coating hydrogen storage materials such as metal hydrides, preventing degradation and improving absorption-release cycles. It is also used to create nanostructured hydrogen storage systems, which increase surface area and improve hydrogen uptake capacity. In fuel cell technology, ALD is employed to create thin, dense electrolyte layers in solid oxide fuel cells (SOFCs) and to improve electrode interfaces, enhancing their long-term stability. For proton exchange membrane fuel cells (PEMFCs), ALD helps reduce the use of expensive platinum group metals (PGMs) by improving the performance and durability of non-PGM catalysts. Similarly, ALD enhances the efficiency of alkaline fuel cells by creating durable, high-performing catalyst layers.

ALD may be critical in improving the performance of catalysts and electrodes used in hydrogen energy systems. It enables the coating of non-precious metal catalysts, enhancing their activity and stability. ALD also provides protective layers on catalysts to prevent degradation in harsh chemical environments, ensuring longer device lifespans. In the development of gas diffusion electrodes (GDEs), ALD improves conductivity, hydrophobicity, and corrosion resistance, making them more efficient for fuel cell applications. Furthermore, ALD can be used to create defect-free membranes for hydrogen purification, which are essential for separating and purifying hydrogen in industrial processes.

Other notable applications include the use of ALD in hydrogen sensors, where thin films created by ALD increase the sensitivity and durability of sensing materials. ALD also plays a key role in corrosion protection for hydrogen infrastructure, such as pipelines and storage tanks, by providing thin, protective layers that resist chemical degradation. In solar-driven hydrogen production, ALD improves the stability and efficiency of photocatalysts and enhances the performance of light absorbers by adding anti-reflective and passivation layers. Additionally, ALD is being explored for use in hybrid energy systems that combine hydrogen storage with battery technologies, further demonstrating its versatility in hydrogen-related applications. Overall, ALD’s precise control over material properties makes it a critical enabling technology for advancing hydrogen energy solutions.

Source:
The authors of "Emerging Atomic Layer Deposition for Hydrogen Energy" are primarily affiliated with the University of Johannesburg, South Africa. Dr. Peter Ozaveshe Oviroh holds a PhD in Mechanical Engineering Science from the University of Johannesburg and focuses on advanced material synthesis and energy systems. Dr. Sunday Temitope Oyinbo is a Specially Appointed Researcher at Kyoto University of Advanced Science in Japan, with expertise in hydrogen energy and materials engineering. Dr. Sina Karimzadeh is a Postdoctoral Research Fellow at the University of Johannesburg, contributing to research on thin-film deposition and nanomaterials. Dr. Patrick Ehi Imoisili is a Senior Lecturer and Researcher at the same institution, specializing in materials science and renewable energy technologies. Professor Tien-Chien Jen, also affiliated with the University of Johannesburg, is an accomplished academic recognized as an ASME Fellow, ASSAf Fellow, and SARChI Chair, with extensive expertise in hydrogen energy systems, nanotechnology, and thermal-fluid sciences. Together, the authors bring a diverse range of expertise in materials engineering, hydrogen energy, and atomic layer deposition technologies.